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==2020 – Present== | |||
165. "Silica Gel–Mediated Rearrangements,“ Wieland, M.; Brecker, L.; Arion, V. B.; Brinker, U. H., in preparation. | |||
164. ''Carbene Rearrangements XCVII'': "The Carbene Route to ...," in preparation. | |||
163. ''Carbene Rearrangements XCVI'': "Carbene Fidget Spinners: Study of a ...," in preparation. | |||
162. "Synthesis of (bicyclo[2.2.0]hex–1–yl)methanal and Arrhenius parameters for thermal rearrangement: radical stabilizing effect of aldehyde substituents on highly strained C–C bonds," Nowienski, A.; Rosenberg, M. G.; Brinker, U. H., '''OpenAccess''' [https://authors.elsevier.com/sd/article/S0040-4039(24)00464-7 ''Tetrahedron Lett.'' '''2024''', ''65'', xxxx – xxxx]. | |||
161. ''Carbene Rearrangements XCV'': "Carbene Routes to Cyclopropatetrahedrane," Rosenberg, M. G.; Brinker, U. H., '''OpenAccess''' [https://www.newkai.com/uhb3/images/f/f4/Rosenberg-brinker-2022-carbene-routes-to-cyclopropatetrahedrane-2.pdf ''J. Org. Chem.'' '''2022''', ''87'', 16902 – 16906]. | |||
160. ''Carbene Rearrangements XCIV'': "Tricyclo[2.1.0.0<sup>2,5</sup>]pent–3–ylidene: Stereoelectronic Control of Bridge-Flapping within a Nonclassical Nucleophilic Carbene," Rosenberg, M. G.; Brinker U. H., '''OpenAccess''' [https://www.newkai.com/uhb3/images/2/25/Rosenberg-brinker-2020-tricyclo-2-1-0-02-5-pent-3-ylidene-stereoelectronic-control-of-bridge-flapping-within-a.pdf ''J. Org. Chem.'' '''2021''', ''86'', 878 – 891]. Twitter [https://twitter.com/JOC_OL/status/1343923528752627714 @JOC_OL] 2020, Dec. 29. | |||
==2015 – 2019== | |||
159. ''Carbene Rearrangements XCIII'': "Bent Singlet Cyclobutylcarbene: Computed Geometry, Properties, and Product Selectivity of a Nonclassical Carbene," Rosenberg, M. G.; Brinker, U. H., [http://dx.doi.org/10.1021/acs.joc.9b01732 ''J. Org. Chem.'' '''2019''', ''84'', 11873 – 11884]. Twitter [https://twitter.com/JOC_OL/status/1166802311575986179 @JOC_OL] 2019, Aug. 28. | |||
158. ''Carbene Rearrangements XCII'': "Diastereoselective Carbenes: Stereoelectronic Control of Bent Singlet ''trans''–2'–Substituted Cyclobutylcarbenes," Rosenberg, M. G.; Brinker, U. H. [https://doi.org/10.1016/j.tetlet.2018.01.006 ''Tetrahedron Lett.'' '''2018''', ''59'', 645 – 649]; featured prominently on the cover of the issue containing this communication. | |||
157. ''Carbene Rearrangements XCI'': "Competitive 1,2–C Atom Shifts in the Strained Carbene Spiro[3.3]hept–1–ylidene Explained by Distinct Ring–Puckered Conformers," Rosenberg, M. G.; Schrievers, T.; Brinker, U. H. [http://pubs.acs.org/doi/pdf/10.1021/acs.joc.6b02445 ''J. Org. Chem.'' '''2016''', ''81'', 12388 – 12400]. | |||
156. ''Carbene Rearrangements XC'': "Intermolecular Reactions of a Foiled Carbene with Carbonyl Compounds: The Effects of Homoaromatic Stabilization." Part of the special JOC issue: "50 Years and Counting: The Woodward–Hoffmann Rules in the 21st Century," Apeland, I. M.; Rosenberg, M. G.; Arion, V. B.; Kählig, H.; Brinker, U. H. [http://pubs.acs.org/doi/pdf/10.1021/acs.joc.5b01988 ''J. Org. Chem.'' '''2015''', ''80'', 11877 – 11887]. Twitter [http://pubs.acs.org/doi/pdf/10.1021/acs.joc.5b01988 @JOC_OL] 2015, Oct. 21. | |||
==2010 – 2014== | |||
155. "Bromination and Accompanying Rearrangements of the Polycyclic Oxetane 2,4–Oxytwistane," Rosenberg, M. G.; Billing, P.; Brecker, L.; Brinker, U. H. [http://pubs.acs.org/doi/pdf/10.1021/jo5016129 ''J. Org. Chem.'' '''2014''', ''79'', 8786 – 8799]. | |||
154. ''Carbene Rearrangements LXXXIX: Carbenes in Constrained Systems XVIII'', “Supramolecular Carbene Chemistry,“ Brinker, U. H.; Mieusset, J.–L.; Rosenberg, M. G. In ''Contemporary Carbene Chemistry,'' Moss, R. A.; Doyle, M. P., Eds., [http://dx.doi.org/10.1002/9781118730379.ch10 Wiley, Hoboken, NJ, USA, 2014, Chapter 10, pp 274 – 323, 4 plates]. | |||
153. ''Carbene Rearrangements LXXXVIII:'' “Probing the Nature and Extent of Stabilization within Foiled Carbenes: Homoallylic Participation by a Neighboring Cyclopropane Ring,“ Apeland, I. M.; Kählig, H.; Lorbeer, E.; Brinker, U. H. [http://pubs.acs.org/doi/pdf/10.1021/jo4004579 ''J. Org. Chem.'' '''2013''', ''78'', 4879 – 4885]. | |||
152. ''Carbene Rearrangements LXXXVII: Carbenes in Constrained Systems XVII'', “Decomposition of an Oxodiazirine: Free versus Incarcerated Within the Cavities of Two ''α''–Cyclodextrins,“ Mieusset, J.–L.; Thiel, B.; Abraham, M.; Pačar, M.; Brinker, U. H. [https://dx.doi.org/10.1016/j.tetlet.2012.12.008 ''Tetrahedron Lett.'' '''2013''', ''54,'' 681 – 683]. | |||
151. “Mild One-Step Synthesis of Dibromo Compounds from Cyclic Ethers,“ Billing, P.; Brinker, U. H. [http://pubs.acs.org/doi/pdf/10.1021/jo302360t ''J. Org. Chem.'' '''2012''', ''77'', 11227 – 11231]. | |||
150. “Cucurbit[6]uril as a Potential Catalyst for the Acidic Decomposition of Azidoamines,“ Wieland, M.; Mieusset, J.–L.; Brinker, U. H. [http://dx.doi.org/10.1016/j.tetlet.2012.06.016 ''Tetrahedron Lett.'' '''2012''', ''53,'' 4351 – 4353]. | |||
149. ''Carbene Rearrangements LXXXVI: Carbenes in Constrained Systems XVI'', “Cucurbituril Adamantanediazirine Complexes and Consequential Carbene Chemistry,“ Gupta, S.; Choudhury, R.; Krois, D.; Brinker, U. H.;* Ramamurthy, V.* [https://www.newkai.com/uhb3/images/7/79/Cucurbituril.pdf ''J. Org. Chem.'' '''2012''', ''77'', 5155 – 5160]; featured twice in the rotating Highlights on the ''J. Org. Chem.'' home page when published in 2012 and again in May 2013. | |||
148. “Solvent Dependency of the Yield of an ''N''–monosubstituted Diaziridine: a GC–MS Study,“ Billing, P.; Brinker, U. H. [http://dx.doi.org/10.1016/j.tetlet.2012.03.105 ''Tetrahedron Lett.'' '''2012''', ''53,'' 2822 – 2824]. | |||
147. ''Carbene Rearrangements LXXXV:'' “Conformations and Reactions of Bicyclo[3.2.1]oct–6–en–8–ylidene,“ Brinker, U. H.; Bespokoev, A. A.; Reisenauer, H. P.; Schreiner, P. R. [http://pubs.acs.org/doi/pdf/10.1021/jo3001035 ''J. Org. Chem.'' '''2012''', ''77'', 3800 – 3807]; featured in the rotating Highlights on the ''J. Org. Chem.'' home page. | |||
146. ''Carbene Rearrangements LXXXIV:'' “Intra– and Intermolecular Reaction Selectivities of γ–Substituted Adamantanylidenes,“ Knoll, W.; Kaneno, D.; Brecker, L.; Bobek, M. M.; Rosenberg, M. G.; Tomoda, S.; Brinker, U. H. [http://pubs.acs.org/doi/pdf/10.1021/jo202132c ''J. Org. Chem.'' '''2012''', ''77'', 1340 – 1360]; featured in the rotating Highlights on the ''J. Org. Chem.'' home page. | |||
145. ''Carbene Rearrangements LXXXIII: Carbenes in Constrained Systems XV'', “Photochemical Generation and Reactivity of Carbenes Within an Organic Cavitand and Capsule: Photochemistry of Adamantanediazirines,“ Gupta, S.; Choudhury, R.; Krois, D.; Wagner, G.; Brinker, U. H.*; Ramamurthy, V.* [https://www.newkai.com/uhb3/images/b/b7/Photochemical_Generation.pdf ''Org. Lett.'' '''2011''', ''13'', 6074 – 6077]. | |||
144. ''Carbene Rearrangements LXXXII:'' “Quest for Even Higher Stabilized Foiled Carbenes,“ Su, K.–J.; Pačar, M.; Mieusset, J.–L.;* Arion, V. B.; Brinker, U. H.* [http://pubs.acs.org/doi/pdf/10.1021/jo201308a ''J. Org. Chem.'' '''2011''', ''76'', 7491 – 7496]. | |||
143. “Emanuel Vogel (1927 – 2011),“ Altenbach, H.–J.; Brinker, U. H.; Klärner, F. G.; Müllen, K. ''Nachrichten aus der Chemie,'' '''2011''', ''59,'' 655 (in German). | |||
142. “Study of the Structure and Photochemical Decomposition of Azidoadamantanes Included in ''α''– and ''β''–Cyclodextrin,“ Brinker, U. H.; Walla, P.; Krois, D.; Arion, V. B. [https://www.newkai.com/uhb3/images/8/87/Study.pdf ''Eur. J. Org. Chem.'' '''2011''', 1249 – 1255]. | |||
141. ''Carbene Rearrangements LXXXI:'' “Efforts toward Distorted Spiropentanes,“ Su, K.–J.; Mieusset, J.–L.; Arion, V. B.; Knoll, W.; Brecker, L.; Brinker, U. H. [http://pubs.acs.org/doi/pdf/10.1021/jo1017298 ''J. Org. Chem.'' '''2010''', ''75'', 7494 – 7497]. | |||
140. “Molecular Encapsulation: Organic Reactions in Constrained Systems,“ Brinker, U. H.; Mieusset, J.–L., Eds., [http://eu.wiley.com/WileyCDA/WileyTitle/productCd-0470998075.html John Wiley & Sons, Chichester, Great Britain, 2010]. | |||
139. ''Carbene Rearrangements LXXX: Carbenes in Constrained Systems XIV'', “Encapsulation of Reactive Intermediates,“ Mieusset, J.–L.; Brinker, U. H. In “Molecular Encapsulation: Organic Reactions in Constrained Systems,“ Brinker, U. H.; Mieusset, J.–L., Eds.,[http://eu.wiley.com/WileyCDA/WileyTitle/productCd-0470998075.html Wiley, Chichester, 2010, Great Britain, pp 269 – 308]. | |||
138. “Solvent– and Temperature–Dependent Co–Conformation of Ferrocenyl Azide inside ''β''–Cyclodextrin: Induced Circular Dichroism–, Quantum Mechanical–, and NMR Studies,“ Walla, P.; Brecker, L.; Brinker, U. H., in preparation. | |||
137. ''Carbene Rearrangements LXXIX:'' “2''H''–Azirines from a Concerted Addition of Alkylcarbenes to Nitrile Groups,“ Knoll, W.; Mieusset, J.–L.; Arion, V. B.; Brecker, L.; Brinker, U. H. [http://pubs.acs.org/doi/pdf/10.1021/ol100703r ''Org. Lett.'' '''2010''', ''12'', 2366 – 2369]. | |||
136. ''Carbene Rearrangements LXXVIII: Carbenes in Constrained Systems XIII'', "Structure–Reactivity Relationships: Reactions of a 5–Substituted Aziadamantane in a Resorcin[4]arene–based Cavitand,“ Wagner, G.; Knoll, W.; Bobek, M. M.; Brecker, L.; van Herwijnen, H. W. G.; Brinker, U. H. [http://pubs.acs.org/doi/pdf/10.1021/ol902667a ''Org. Lett.'' '''2010''', ''12'', 332 – 335]. | |||
==2005 – 2009== | |||
135. ''Carbene Rearrangements LXXVII: Carbenes in Constrained Systems XII'', “Supramolecular Photochirogenesis with Carbenes Entrapped in Cyclodextrins,“ Mieusset, J.–L.; Wagner, G.; Su, K.–J.; Steurer, M.; Pačar, M.; Abraham, M.; Brinker, U. H [https://doi.org/10.1002/ejoc.200900899 ''Eur. J. Org. Chem.'' '''2009''', 5907 – 5912]. | |||
134. “Controllable Selective Functionalization of a Cavitand via Solid State Photolysis of an Encapsulated Phenyl Azide,“ Wagner, G.; Arion, V. B.; Brecker, L.; Krantz, C.; Mieusset, J.–L.; Brinker, U. H. [https://www.newkai.com/uhb3/images/9/97/Controllable.pdf ''Org. Lett.'' '''2009''', ''11'', 3056 - 3058]; featured in the rotation highlights on the ''Org. Lett.'' home page. | |||
133. “1,2,4,5-Tetrakis(diazidomethyl)benzene,“ Wieland, M.; Su, K.–J.; Wagner, G.; Brinker, U. H.; Arion, V. B.* [http://doi.org/10.1107/S0108270109013894 ''Acta Cryst.'' '''2009''', ''C65'', o240 – o242]. | |||
132. ''Carbene Rearrangements LXXVI:'' “Stepwise Insertion of Carbenes into C–H Bonds: The Case of Foiled Carbenes,“ Mieusset, J.–L; Schrems, A.; Abraham, M.; Arion, V. B.; Brinker, U. H. [https://doi.org/10.1016/j.tet.2008.11.063 ''Tetrahedron'', '''2009''', ''65'', 765 – 770]. | |||
131. “Thermal Ring Opening of 1,1–Dibromo– and 1–Bromo–2–chloromethylcyclopropanes: Observation of a Formal Debromochlorination, “ Sydnes, L. K.;* Alnes, K. F.; Pettersen, A.; Brinker, U. H. [https://www.newkai.com/uhb3/images/d/d8/S00706-008-0076-4.pdf ''Monatsh. Chem.'' '''2009''', ''140'', 479 – 483]. | |||
130. ''Carbene Rearrangements LXXV:'' “Carbene–Alkene–Complexes between a Nucleophilic Carbene and Electron–Poor Alkenes,“ Mieusset, J.–L; Abraham, M.; Brinker, U. H. [http://pubs.acs.org/doi/pdf/10.1021/ja8042118 ''J. Am. Chem. Soc.'' '''2008''', ''130'', 14634 – 14639]. | |||
129. ''Carbene Rearrangements LXXIV:'' “2–Methoxy–Δ<sup>3</sup>–1,3,4–oxadiazoline, a Multipurpose Precursor for the Generation of a Carbene, an Ylide, or a Diazo Compound,“ Mieusset, J.–L; Billing, P.; Abraham, M.; Arion, V. B.; Brecker, L.; Brinker, U. H. [https://doi.org/10.1002/ejoc.200800709 ''Eur. J. Org. Chem.'' '''2008''', 5336 – 5345]. | |||
128. ''Carbene Rearrangements LXXIII:'' “Substituent Effects on the Ring Opening Mechanism of Lithium Bromocyclopropylidenoids to Allenes,“ Azizoglu, A.;* Balci, M.; Mieusset, J.–L.; Brinker, U. H. [http://pubs.acs.org/doi/pdf/10.1021/jo8011144 ''J. Org. Chem.'' '''2008''', ''73'', 8182 – 8188]. | |||
127. ''Carbene Rearrangements LXXII:'' “Intermolecular Reactions of Foiled Carbenes with N–H Bonds: Evidence for an Ylidic Pathway,“ Mieusset, J.–L.; Bespokoev, A.; Pačar, M.; Abraham, M.; Arion, V. B.; Brinker, U. H. [http://pubs.acs.org/doi/pdf/10.1021/jo800802m ''J. Org. Chem.'' '''2008''', ''73'', 6551 – 6558]. | |||
126. “Molecular Dynamics Simulation of Configurational Properties of Complexes between β–Cyclodextrin and 2,6–Diaziadamantane in Water, “ Zifferer, G.;* Kornherr, A.; Brinker, U. H. [http://www.tandfonline.com/doi/pdf/10.1080/08927020802193145 ''Molecular Simulation'', '''2008''', ''34'', 1177 – 1183]. | |||
125. ''Carbene Rearrangements LXXI:'' “Reactions of Carbenes with Ethers: The Role of Noncovalent Interactions,“ Mieusset, J.–L.; Brinker, U. H. [https://doi.org/10.1002/ejoc.200800256 ''Eur. J. Org. Chem.'' '''2008''', 3363 – 3368]. | |||
124. ''Carbene Rearrangements LXX:'' “The Carbene Reactivity Surface: A Classification,“ Mieusset, J.–L.;* Brinker, U. H.* [http://pubs.acs.org/doi/pdf/10.1021/jo7026118 ''J. Org. Chem.'' '''2008''', ''73'', 1553 – 1558]. | |||
123. “Molecular Dynamics Simulations of ''β''–Cyclodextrin–Aziadamantane Complexes in Water,“ Sellner, B.; Zifferer, G.;* Kornherr, A.; Krois, D.; Brinker, U. H. [https://doi.org/10.1021/jp075493+ ''J. Phys. Chem. B'' '''2008''', ''112'', 710 – 714]. | |||
122. ''Carbene Rearrangements LXIX:'' “Toward Selective Reactions with C–H Bonds: A Rationale for the Regio– and Stereochemistry of Dichlorocarbene Insertions into Cyclic Hydrocarbons,“ Mieusset, J.–L.; Brinker, U. H. [http://pubs.acs.org/doi/pdf/10.1021/jo702047b ''J. Org. Chem.'' '''2007''', ''72'', 10211 – 10219]. | |||
121. ''Carbene Rearrangements LXVIII:'' “Dihalocarbene Insertion Reactions into C–H Bonds of Compounds Containing Small Rings: Mechanisms and Regio– and Stereoselectivities,” Brinker, U. H.; Lin, G.; Xu, L.; Smith, W. B.; Mieusset, J.–L. [https://doi.org/10.1021/jo7013356 ''J. Org. Chem.'' '''2007''', ''72'', 8434 – 8451]. | |||
120. “Sugary Carbene," Brinker, U. H., ''Chem. Eng. News'', '''2007''', ''85'', May 7, p. 8. | |||
119. ''Carbene Rearrangements LXVII:'' “Cope Rearrangement versus a Novel Tandem Retro–Diels–Alder–Diels–Alder Reaction with Role Reversal,” Su, K.–J.; Mieusset, J.–L.; Arion, V. B.; Brecker, L.; Brinker, U. H. [https://doi.org/10.1021/ol0626793 ''Org. Lett.'' '''2007''', ''9'', 113 – 115]. | |||
118. ''Carbene Rearrangements LXVI:'' “Foiled Carbenes Revisited: When σ–Stabilization Surpasses π–Stabilization,” Mieusset, J.–L.; Brinker, U. H. [http://pubs.acs.org/doi/pdf/10.1021/jo062074k ''J. Org. Chem.'' '''2007''', ''72'', 263 – 268]. | |||
117. ''Carbene Rearrangements LXV:'' “The Nature and Extent of π–Stabilization within Foiled Carbenes,” Mieusset, J.–L.; Brinker, U. H. [http://pubs.acs.org/doi/pdf/10.1021/ja065595y ''J. Am. Chem. Soc.'' '''2006''', ''128'', 15843 – 15850]. | |||
116. ''Carbene Rearrangements LXIV: Carbenes in Constrained Systems XI''. Invited Microreview on “Constrained Carbenes,” Rosenberg, M. G.; Brinker U. H. [https://doi.org/10.1002/ejoc.200600547 ''Eur. J. Org. Chem.'' '''2006''', 5423 – 5440]. | |||
115. “Circular Dichroism of Cyclodextrin Complexes”, Krois, D.; Brinker U. H. In ''Handbook of Cyclodextrins and Their Complexes,'' Dodziuk, H., Ed., [http://dx.doi.org/10.1002/3527608982 Wiley-VCH, Weinheim, 2006, Chapter 10.4, pp 289 – 298]. | |||
114. ''Carbene Rearrangements LXIII'': “Reactions of ''endo''–3–Diazotricyclo[3.2.1.0<sup>2,4</sup>]oct–6–ene, a Potential Precursor for the Generation of a Neutral C<sub>8</sub>H<sub>8</sub> Molecule with a Pyramidally Coordinated Carbon,” Mieusset, J.–L.; Brinker, U. H. [https://doi.org/10.1021/jo061082y ''J. Org. Chem.'' '''2006''', ''71'', 6975 – 6982]. | |||
113. “Solvent– and Temperature–Tuned Orientation of Ferrocenyl Azide Inside ''β''–Cyclodextrin,” Walla, P.; Arion, V. B.; Brinker, U. H. [http://pubs.acs.org/doi/pdf/10.1021/jo060102t ''J. Org. Chem.'' '''2006''', ''71'', 3274 – 3277]. | |||
112. ''Carbene Rearrangements LXII'': “On the Existence of Uncharged Molecules with a Pyramidally Coordinated Carbon: the Cases of Pentacyclo[4.3.0.0<sup>2,9</sup>.0<sup>3,8</sup>.0<sup>7,9</sup>]non-4-ene and Heptacyclo[7.6.0.0<sup>1,5</sup>.0<sup>5,15</sup>.0<sup>6,14</sup>.0<sup>10,14</sup>.0<sup>10,15</sup>]pentadecane,” Mieusset, J.–L.; Brinker, U. H. [http://pubs.acs.org/doi/pdf/10.1021/jo051847m ''J. Org. Chem.'' '''2005''', ''70'', 10572 – 10575]. | |||
111. ''Carbene Rearrangements LXI: Carbenes in Constrained Systems X'' ,“Carbenes Generated within Cyclodextrins and Zeolites,” Rosenberg, M. G.; Brinker, U. H. In ''Adv. Phys. Org. Chem.,'' Richard, J. P., Ed., [http://dx.doi.org/10.1016/s0065-3160(05)40001-5 Academic Press, New York, 2005, Vol. 40, Chapter 1, pp 1 – 47]. | |||
110. “1–''H''–Cyclobuta[''a'']naphthalen–2–one,” Neudeck, H.; Brinker, U. H. [https://doi.org/10.1016/j.tetlet.2005.01.083 ''Tetrahedron Lett.'' '''2005''', ''46'', 1893 – 1895]. | |||
==2000 – 2004== | |||
109. ''Carbene Rearrangements LX: Carbenes in Constrained Systems IX'', “Supramolecular Structure – Reactivity Relationships: Photolysis of a Series of Aziadamantane@Cyclodextrin Inclusion Complexes in the Solid State,” Krois, D.; Brecker, L.; Werner, A.; Brinker, U. H. [https://doi.org/10.1002/adsc.200404142 ''Adv. Synth. Catal.'' '''2004''', ''346'', 1367 – 1374]. | |||
108. “Supramolecular Recognition and Structural Elucidation of Inclusion Complexes of an Achiral Carbene Precursor in ''β''– and Permethylated ''β''–Cyclodextrin,” Mieusset, J.–L.; Krois, D.; Pacar, M.; Brecker, L.; Giester, G.; Brinker, U. H. [https://www.newkai.com/uhb3/images/f/fc/Supramolecular.pdf ''Org. Lett.'' '''2004''', ''6'', 1967 – 1970]. | |||
107. “Innermolecular Carbene Reactions within Cyclodextrins,” Mieusset, J.–L.; Brinker, U. H. ''Chem. Listy'' '''2004''', ''98'', 50 – 51. | |||
106. ''Carbene Rearrangements LIX:'' "Regioselective Formation of Alkylidenecyclopropanes from 2–Substituted Cyclobutylidenes Generated from Geminal Dibromocyclobutanes with Methyllithium," Nordvik, T.; Mieusset, J.–L.; Brinker, U. H. [http://pubs.acs.org/doi/abs/10.1021/ol036348r ''Org. Lett.'' '''2004''', ''6'', 715 – 718]. | |||
105. “A Novel Route to Geminal Dibromocyclobutanes: Syntheses of 2–Substituted Cyclobutanone Acetals and Their Reaction with Boron Tribromide,” Nordvik, T.; Brinker, U. H. [http://pubs.acs.org/doi/abs/10.1021/jo035295o ''J. Org. Chem.'' '''2003''', ''68,'' 9394 – 9399]. | |||
104. “Thermolysis of 1-(1-Aryl-1-bromomethyl)cyclopropyl Bromides: A Reinvestigation,” Nordvik, T.; Brinker, U. H. [http://pubs.acs.org/doi/abs/10.1021/jo034431m ''J. Org. Chem.'' '''2003''', ''68'', 7092 – 7093]. | |||
103. ''Carbene Rearrangements LVIII:'' "Reversal of Diastereoselectivities in Intra– and Intermolecular Reactions of 2–Adamantylidenes Primarily Caused by Electron–Donating and Electron–Withdrawing Substituents on C5,” Knoll, W.; Bobek, M. M.; Kalchhauser, H.; Rosenberg, M. G.; Brinker, U. H. [https://doi.org/10.1021/ol0350700 ''Org. Lett.'' '''2003''', ''5'', 2943 – 2946]. | |||
102. ''Carbene Rearrangements LVII:'' ''Carbenes in Constrained Systems VIII'', "Inter– and Innermolecular Reactions of Chloro(phenyl)carbene,“ Rosenberg, M. G.; Brinker, U. H. [http://pubs.acs.org/doi/abs/10.1021/jo026521h ''J. Org. Chem.'' '''2003''', ''68'', 4819 – 4832]. | |||
101. "2,6–Diaziadamantane: A Single Crystal X–ray Diffraction Study and Theoretical Calculations," Bobek, M. M; Krois, D.; Brehmer, T. H.; Giester, G.; Wiberg, K. B.; Brinker, U. H. [http://pubs.acs.org/doi/abs/10.1021/jo020536y ''J. Org. Chem.'' '''2003''', ''68'', 2129 – 2134]. | |||
100. "Insights into Regioselective Oxy (–O–) and Imino (–NH–) Group Insertions of 3–Nortricyclanone," Rosenberg, M. G.; Haslinger, U.; Brinker, U. H. [http://pubs.acs.org/doi/abs/10.1021/jo0159587 ''J. Org. Chem.'' '''2002''', ''67'', 450 – 456]. | |||
99. "Probing the Active Catalytic Sites of Zeolites with Benzyl Chloride," van Herwijnen, H. W. G.; Brinker, U. H. [https://doi.org/10.1016/S0040-4020(02)00409-X ''Tetrahedron'' '''2002''''', 58'', 4963 – 4967]. | |||
98. ''Carbene Rearrangements LVI.'' "4–Aziadamantan–1–amine: Synthesis, Reactions, and Cyclodextrin Complexes," Knoll, W.; Bobek, M. M.; Giester, G.; Brinker, U. H. [https://doi.org/10.1016/S0040-4039(01)02013-5 ''Tetrahedron Lett''. '''2001''', ''42'', 9161 – 9165]. | |||
97. ''Advances in Carbene Chemistry'', Vol. 3, Brinker, U. H., Ed. [https://books.google.at/books?id=7Nz30IWc7k0C&printsec=frontcover&hl=de&source=gbs_ge_summary_r&cad=0, Elsevier, Amsterdam, The Netherlands, 2001]. | |||
96. "''Meta'' Selectivity in the Friedel–Crafts Reaction Induced by a Faujasite–type Zeolite," van Herwijnen, H. W. G.; Brinker, U. H. [http://pubs.acs.org/doi/abs/10.1021/jo005716r ''J. Org. Chem.'' '''2001''', ''66'', 2874 – 2876]. | |||
95. "Synthesis of a Sterically Hindered Diazirine with a Satisfactory Yield: Optically Active 2–Azicamphane“, Krois, D.; Brinker, U. H. [https://doi.org/10.1055/s-2001-11450 ''Synthesis'' '''2001''', 379 – 381]. | |||
94. "A Novel and Facile Synthesis of 2,3–Diphenyl–1,3–butadiene," Wagner, R. A.; Brinker, U. H. [https://doi.org/10.1055/s-2001-11448 ''Synthesis'' '''2001''', 376 – 378]. | |||
93. ''Carbene Rearrangements LV:'' ''Carbenes in Constrained Systems VII'', "Effect of Supramolecular Constraint on the Selectivity of 3–Nortricyclanylidene," Rosenberg, M. G.; Brinker, U. H. [http://pubs.acs.org/doi/abs/10.1021/jo005713e ''J. Org. Chem''. '''2001''', ''66'', 1517 – 1522]. | |||
92. "Induced Circular Dichroism of Cyclodextrin Inclusion Complexes: Examining the Cavity with a Bilateral Probe,“ Bobek, M. M.; Krois, D.; Brinker, U. H. [http://pubs.acs.org/doi/pdf/10.1021/ol005923d ''Org. Lett''. '''2000''', ''2'', 1999 – 2002]. | |||
91. ''Carbene Rearrangements LIV'': "Intra- and Intermolecular Diastereoselectivity of 5–Hydroxy–2–adamantylidene." Bobek, M. M.; Brinker, U. H. [http://pubs.acs.org/doi/abs/10.1021/ja001123m ''J. Am. Chem. Soc''. '''2000''', ''122'', 7430 – 7431]. | |||
90. "A 'Sugar–coated' Carbene Precursor: A Single Crystal X–ray Diffraction and NMR Study", Bobek, M. M.; Giester, G.; Kählig, H.; Brinker, U. H. [https://doi.org/10.1016/S0040-4039(00)00938-2 ''Tetrahedron Lett''. '''2000''', ''41'', 5663 – 5667]. | |||
89. ''Carbene Rearrangements LIII:'' "Addition of Dichloro– and Dibromocarbene to 1,2–Diphenylcyclobutene,“ Wagner, R. A.; Weber, J.; Brinker, U. H. [http://dx.doi.org/10.1246/cl.2000.246 ''Chemistry Lett''. '''2000''', 246 – 247]. | |||
88. ''Carbene Rearrangements LII:'' ''Carbenes in Constrained Systems VI'', "Chemospecific Monofunctionalization of ''α''–Cyclodextrin in the Solid State," Krois, D.; Bobek, M. M.; Werner, A.; Kählig, H.; Brinker, U. H. [http://pubs.acs.org/doi/pdf/10.1021/ol9912635 ''Org. Lett''. '''2000''', ''2'', 315 – 318]. | |||
87. "Cyclopropene: A New Simple Synthesis and its Diels–Alder Reaction with Cyclopentadiene," Binger, P.; Wedemann, P.; Brinker, U. H. [http://dx.doi.org/10.15227/orgsyn.077.0254 ''Org. Synth.'' '''2000''', ''77'', 254 – 259]. | |||
==1995 – 1999== | |||
86. "A Facile One–step Synthesis of 2,4–Adamantanedione," Bobek, M. M.; Brinker, U. H. [https://doi.org/10.1080/00397919908085947 ''Synthetic Commun''. '''1999''', ''29'', 3221 – 3225]. | |||
85. ''Carbene Rearrangements LI:'' "Competitive Intramolecular Reactions of ''n''–Alkenyl- and ''n''–Alkyl–substituted Cyclopropylidenes: An Insertion Reaction into Non–activated C–H Bonds,” Brinker, U. H.; Miebach, T. [http://pubs.acs.org/doi/abs/10.1021/jo990972t ''J. Org. Chem''. '''1999''', ''64'', 8000 – 8003]. | |||
84. ''Carbene Rearrangements L:'' "1–Bromobicyclo[1.1.0]butane as an Easily Obtainable C4–Building Block: A Novel Route to Cyclobutanone," Weber, J.; Haslinger, U.; Brinker, U. H. [http://pubs.acs.org/doi/abs/10.1021/jo980190k ''J. Org. Chem''. '''1999''', ''64'', 6085 – 6086]. | |||
83. ''Carbene Rearrangements XLIX:'' "Preparation of 7,7–Dibromobicyclo[4.1.0]heptane," Xu, L.; Brinker, U. H. In "Synthetic Organic Sonochemistry," Luche, J.–L., Ed. [https://doi.org/10.1007/978-1-4899-1910-6_9 Springer, Boston, MA, 1998, 344 – 345]. | |||
82. "Induced Circular Dichroism and UV–''vis'' Absorption Spectroscopy of Cyclodextrin Inclusion Complexes: Structural Elucidation of Supramolecular Azi–adamantane (Spiro[adamantane–2,3’–diazirine])," Krois, D.; Brinker, U. H. [http://pubs.acs.org/doi/abs/10.1021/ja982299f ''J. Am. Chem. Soc''., '''1998''', ''120'', 11627 – 11632]. | |||
81. ''Advances in Carbene Chemistry'', Vol. 2, Brinker, U. H., Ed. [http://dx.doi.org/10.1021/ja985703j JAI Press, Stamford, CT, USA, 1998]. | |||
80. ''Carbene Rearrangements XLVIII:'' ''Carbenes in Constrained Systems V''. "Chemistry of Carbenes in Molecular Reaction Vessels," Brinker, U. H., Rosenberg, M. G. In ''Advances in Carbene Chemistry'', Vol. 2, Brinker, U.H., Ed., [http://dx.doi.org/10.1016/s1079-350x(98)80004-x JAI Press, Stamford, CT, 1998, 29 – 44]. | |||
79. ''Carbene Rearrangements XLVII:'' "Evidence for a Stepwise Addition of Carbenes to Strained Double Bonds: Reactions of Dihalocarbenes with Cyclopropenes," Weber, J.; Brinker, U. H. [https://doi.org/10.1002/anie.199716231 ''Angew. Chem.'' '''1997''', ''109'', 1689 – 1692]; [https://doi.org/10.1002/anie.199716231 ''Angew. Chem., Int. Ed. Engl.'' '''1997''', ''36'', 1623 – 1626]. | |||
78. ''Carbene Rearrangements XLVI:'' "Competing 1,n–Elimination Reactions of 1–Bromo–5–bromomethyl–6,6–dichlorobicyclo[3.1.0]hexane: A Strained 1,3–Bridged Cyclopropene and a Vinylcarbene as Reactive Intermediates," Weber, J.; Brinker, U. H. [https://doi.org/10.1016/0040-4020(96)00912-X ''Tetrahedron'' '''1996''', ''52'', 14641 – 14650]. | |||
77. "Synthesis of a Sterically Congested Diazirine: 2–Azi–camphane," Kupfer, R.; Rosenberg, M. G.; Brinker, U. H. [https://doi.org/10.1016/S0040-4039(96)01497-9 ''Tetrahedron Lett.'' '''1996''', ''37'', 6647 – 6648]. | |||
76. “Cyclopropene: A New Simple Synthesis and Diels–Alder Reactions with Cyclopentadiene and 1,3-Diphenylisobenzofuran," Binger, P.; Wedemann, P.; Goddard, R.; Brinker, U. H. [http://pubs.acs.org/doi/abs/10.1021/jo960728r ''J. Org. Chem.'' '''1996,''' ''61'', 6462 – 6464]. | |||
75. ''Carbene Rearrangements XLV: "Carbenes in Constrained Systems IV.'' Encapsulation of an Asymmetric Diazirine: Reactivity of 2–Methylcyclohexanylidene," Rosenberg, M. G.; Kam, S. M.; Brinker, U. H. [https://doi.org/10.1016/0040-4039(96)00531-X ''Tetrahedron Lett.'' '''1996''', ''37'', 3235 – 3238]. | |||
74. “Cyclopropene Yields Pumped up," ''Chem. Eng. News'', '''1996''', Sept. 23, p. 50. | |||
73. "A Novel Synthesis of Aromatic ''N''–Chloro Aldimines," Kupfer, R.; Brinker, U. H. [http://pubs.acs.org/doi/abs/10.1021/jo960171f ''J. Org. Chem.'' '''1996''', ''61'', 4185 – 4186]. | |||
72. ''Carbene Rearrangements XLIV:'' ''Carbenes in Constrained Systems III.'' "Solid State Photolysis of Spirocycloheptane and Spirocyclooctane Diazirine within Cyclodextrins and Zeolites," Kupfer, R.; Brinker, U. H. [https://doi.org/10.1002/jlac.1995199510242 ''(EurJOC) Liebigs Ann.'' '''1995''', 1721 – 1725]. | |||
==1990 – 1994== | |||
71. ''Carbene Rearrangements XLIII: Carbenes in Constrained Systems II.'' First Carbene Reactions within Zeolites: Solid State Photolysis of Adamantane–2–spiro–3'–diazirine," Kupfer, R.; Poliks, M. D.; Brinker, U. H. [http://pubs.acs.org/doi/abs/10.1021/ja00095a049 ''J. Am. Chem. Soc.'' '''1994''', ''116'', 7393 – 7398]. | |||
70. "Effect of Cyclodextrin on the Intermolecular Photoalkoxycarbonylmethlylation of Anisole," Bantu, N. R.; Kupfer, R.; Brinker, U. H. [https://doi.org/10.1016/S0040-4039(00)77042-0 ''Tetrahedron Lett.'' '''1994''', ''35'', 5117 – 5120]. | |||
69. ''Advances in Carbene Chemistry,'' Vol. 1, Brinker, U. H., Ed. [https://books.google.at/isbn=0080545912, JAI Press, Greenwich, CT, USA, 1994]. | |||
68. "''trans''–Tricyclo[5.1.0.0<sup>1,3</sup>]octane," Miebach, T.; Brinker, U. H. [http://pubs.acs.org/doi/abs/10.1021/jo00075a068 ''J. Org. Chem.'' '''1993''', ''58'', 6524 – 6525]. | |||
67. ''Carbene Rearrangements XLII:'' "Intramolecular Addition ''versus'' Novel Carbon–Hydrogen Bond Insertion Reactions of ''n''–Alkenyl Substituted Cyclopropylidenes," Miebach, T.; Wüster, H.; Brinker, U. H. [http://pubs.acs.org/doi/abs/10.1021/jo00075a067 ''J. Org. Chem.'' '''1993''', ''58'', 6520 – 6523]. | |||
66. ''Carbene Rearrangements XLI:'' ''Carbenes in Constrained Systems I.'' 1,3 Carbon– Hydrogen Bond Insertion Reaction of Adamantylidene within the ''ß''–Cyclodextrin Cavity," Brinker, U. H.; Buchkremer, R.; Kolodziejczyk, M.; Kupfer, R.; Rosenberg, M.; Poliks, M. D.; Orlando, M.; Gross, M. L. [https://doi.org/10.1002/anie.199313441 ''Angew. Chem.'' '''1993''', ''105'', 1427 – 1429]; [https://doi.org/10.1002/anie.199313441 ''Angew. Chem., Int. Ed. Engl.'' '''1993''', ''32,'' 1344 – 1346]. | |||
65. "Proton NMR Studies of ''syn''– and ''anti''–Tricyclo[5.1.0.0<sup>3,5</sup>]octanes and Their Dichloromethyl Derivatives," Xu, L.; Brinker, U. H.; Smith, W. B. [https://doi.org/10.1002/mrc.1260301208 ''Magn. Reson. Chem.'' '''1992''', ''30'', 1196 – 1202]. | |||
64. ''Carbene Rearrangements XL:'' "Efficient Syntheses of Multisubstituted Methylenecyclopropanes via Novel Ultrasonicated Reactions of 1,1–Dihaloolefins and Metals," Xu, L.; Lin, G.; Tao, F.; Brinker, U. H. [http://actachemscand.org/pdf/acta_vol_46_p0650-0653.pdf ''Acta Chem. Scand.'' '''1992''', ''B46'', 650 – 653]. | |||
63. ''Carbene Rearrangements XXXIX:'' "First Formation of 1,1–Dihalo–1,3–butadienes from Reactions of Dichloro– and Dibromocarbene with Cyclopropenes via New Addition–Rearrangements," Weber, J.; Xu, L.; Brinker, U. H. [https://doi.org/10.1016/S0040-4039(00)61306-0 ''Tetrahedron Lett.'' '''1992''', ''33'', 4537 – 4540]. | |||
62. ''Carbene Rearrangements XXXVIII:'' "Functionalization of Saturated Hydrocarbons: Selective Insertion Reactions of Dihalocarbenes into Carbon–Hydrogen Bonds Adjacent to Cyclopropane Rings," Xu, L.; Smith, W. B.; Brinker, U. H. [http://pubs.acs.org/doi/abs/10.1021/ja00028a068 ''J. Am. Chem. Soc.'' '''1992''', ''114,'' 783 – 784]. | |||
61. ''Carbene Rearrangements XXXVII:'' "A New Mechanism for Reactions of Carbenes and Bicyclo[1.1.0]butanes," Xu, L.; Miebach, T.; Smith, W. B.; Brinker, U. H. [https://doi.org/10.1016/0040-4039(91)80012-U ''Tetrahedron Lett.'' '''1991''', ''32'', 4461 – 4464]. | |||
60. "NMR Examination of Tricyclo[4.2.0.0<sup>1,3</sup>]octane," Smith, W. B.; Brinker, U. H. [https://doi.org/10.1002/mrc.1260290510 ''Magn. Reson. Chem.'' '''1991''', ''29'', 465 – 467]. | |||
59. "The Reaction of Cyclopropabenzene with 1,3–Diphenylisobenzofuran: Formal [4π + 2π] and [4π + 2σ] Cycloadditions," Brinker, U. H.; Wüster, H. [https://doi.org/10.1016/S0040-4039(00)74835-0 ''Tetrahedron Lett.'' '''1991''', ''32'', 593 – 596]. | |||
58. "Removal of Calcareous Incrustation from Bone and Teeth with Acid and Ultrasound," Stahl, P. W.; Brinker, U. H. [http://www.jstor.org/stable/530161 ''Journal of Field Archaeology,'' '''1991''', ''18'', 138 – 140]. | |||
57. "A Convenient and Improved Technique to Reduce Substantially the Problem of 'Bumping' When Using a Rotary Evaporator," Buchkremer, R.; Brinker, U. H. [http://jchemed.chem.wisc.edu/Journal/Issues/1990/Dec/jceSubscriber/JCE1990p1071.pdf ''J. Chem. Educ.'' '''1990''', ''67'', 1071]. | |||
56. ''Carbene Rearrangements XXXVI:'' Intramolecular Reactions of Diazocyclobutanes. Synthesis of Tricyclo[4.2.0.0<sup>1,3</sup>]octane ([3.5.4]Fenestrane),” Brinker, U. H.; Schrievers, T.; Xu, L. [http://pubs.acs.org/doi/abs/10.1021/ja00179a070 ''J. Am. Chem. Soc.'' '''1990''', ''112'', 8609 – 8611]. | |||
55. ''Festschrift for Wolfgang Kirmse,'' Brinker, U. H., Ed., The State University of New York at Binghamton, Binghamton, NY, USA, 1990. | |||
==1985 – 1989== | |||
54. ''Carbene Rearrangements XXXV:'' "Heterocycloalkylidenes," Brinker, U. H.; Erdle, W. In ''Houben–Weyl (Methods in Organic Chemistry),'' Vol. E19b, pp. 623 – 663, Thieme, Stuttgart, 1989 (in German). | |||
53. ''Carbene Rearrangements XXXIV:'' "(2 + X)–Cycloalkenylidenes," Brinker, U. H.; Fermann, M. In ''Houben–Weyl (Methods in Organic Chemistry)'', Vol. E19b, pp. 607 – 622, Thieme, Stuttgart, 1989 (in German). | |||
52. ''Carbene Rearrangements XXXIII:'' "Higher Cycloalkylidenes," Sydnes, L.; Brinker, U. H. In ''Houben–Weyl (Methods in Organic Chemistry)'', Vol. E19b, pp. 601 – 606, Thieme, Stuttgart, 1989 (in German). | |||
51. ''Carbene Rearrangements XXXII:'' "Cyclohexylidenes," Sydnes, L.; Brinker, U. H. In ''Houben–Weyl (Methods in Organic Chemistry)'', Vol. E19b, pp. 577 – 600, Thieme, Stuttgart, 1989 (in German). | |||
50. ''Carbene Rearrangements XXXI:'' "Cyclopentylidenes," Sydnes, L.; Brinker, U. H. In ''Houben–Weyl (Methods in Organic Chemistry)'', Vol. E19b, pp. 542 – 576, Thieme, Stuttgart, 1989 (in German). | |||
49. ''Carbene Rearrangements XXX:'' "Cyclobutylidenes," Backes, J.; Brinker, U. H. In ''Houben–Weyl (Methods in Organic Chemistry)'', Vol. E19b, pp. 511 – 541, Thieme, Stuttgart, 1989 (in German). | |||
48. ''Carbene Rearrangements XXIX:'' "Cyclopropylidenes," Backes, J.; Brinker, U. H. In ''Houben–Weyl (Methods in Organic Chemistry)'', Vol. 19b, pp. 391 – 510, Thieme, Stuttgart, 1989 (in German). | |||
47. ''Carbene Rearrangements XXVIII:'' "Higher Cycloalkyl– and Cycloalkyl–organo–carbenes," Brinker, U. H.; Erdle, W. In ''Houben–Weyl (Methods in Organic Chemistry)'', Vol E19b, pp. 388 – 390, Thieme, Stuttgart, 1989 (in German). | |||
46. ''Carbene Rearrangements XXVII:'' "Cyclohexyl– and Cyclohexyl–organo–carbenes," Brinker, U. H.; Erdle, W. In ''Houben–Weyl (Methods in Organic Chemistry)'', Vol. E19b, pp. 385 – 387, Thieme, Stuttgart, 1989 (in German). | |||
45. ''Carbene Rearrangements XXVI:'' "Cyclopentyl– and Cyclopentyl–organo–carbenes," Brinker, U. H.; Erdle, W. In ''Houben–Weyl (Methods in Organic Chemistry)'', Vol. E19b, pp. 379 – 384, Thieme, Stuttgart, 1989 (in German). | |||
44. ''Carbene Rearrangements XXV:'' "Cyclobutyl– and Cyclobutyl–organo–carbenes," Brinker, U. H.; Erdle, W. In ''Houben–Weyl (Methods in Organic Chemistry)'', Vol. E19b, pp. 376 – 378, Thieme, Stuttgart, 1989 (in German). | |||
43. ''Carbene Rearrangements XXIV:'' "Cyclopropylcarbenes," Arct, J.; Brinker, U. H. In ''Houben–Weyl (Methods in Organic Chemistry)'', Vol. E19b, pp. 337 – 375, Thieme, Stuttgart, 1989 (in German). | |||
42. "Spiropentane as a Tensile Spring," Boese, R.; Bläser, D.; Gomann, K.; Brinker, U. H. [http://pubs.acs.org/doi/abs/10.1021/ja00186a058 ''J. Am. Chem. Soc.'' '''1989''', ''111'', 1501 – 1503]. | |||
41. "1,2,4,5-Tetravinylbenzene," Schrievers, T.; Brinker, U. H. [https://www.researchgate.net/publication/235800799_1245-Tetravinylbenzene ''Synthesis'' '''1988,''' 330 – 331]. | |||
40. ''Carbene Rearrangements XXIII:'' "Reactions of 2,2,4,4–Tetramethyl–3–methylenecyclobutylidene; Thermal Rearrangements of a 2–Methylenebicyclo[2.1.0]pentane," Brinker, U. H.; Erdle, W. [http://www3.interscience.wiley.com/cgi-bin/abstract/112231978/ABSTRACT ''Angew. Chem.'' '''1987''', ''99,'' 1290 – 1292]; [https://www.newkai.com/uhb3/images/c/ca/Methylenecyclobutylidene_Thermal.pdf ''Angew. Chem., Int. Ed. Engl.'' '''1987''', ''26'', 1260 – 1262]. | |||
39. "Dicyclopropa[''a,c'']naphthalene: A Compound Capable of Existence?" Brinker, U. H.; Wüster, H.; Maas, G. [http://onlinelibrary.wiley.com/doi/abs/10.1002/anie.198705771 ''Angew. Chem.'' '''1987,''' ''99'', 585 – 586]; [https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.198705771 ''Angew. Chem., Int. Ed. Engl.'' '''1987''', ''26'', 577 – 578]. | |||
38. ''Carbene Rearrangements XXII:'' "Labeling Studies of the Reaction of 8,8–Dibromobicyclo[5.1.0]octa–2,4–diene with Methyl Lithium," Fleischhauer, I.*; Brinker, U. H.* [https://doi.org/10.1002/cber.19871200409 ''Chem. Ber.'' '''1987''', ''120'', 501 – 506]. | |||
37. ''Carbene Rearrangements XXI:'' "1,2–Dimethylspiro[2.3]hex–1–ene by Addition of Cyclobutylidene to 2–Butyne," Brinker, U. H.; Weber, J. [https://doi.org/10.1016/S0040-4039(00)85213-2 ''Tetrahedron Lett.'' '''1986''', ''27'', 5371 – 5374]. | |||
36. "The Electronic Structure of Spiropentane and Some Derivatives," Gleiter, R.; Krennrich, G.; Brinker, U. H. [http://pubs.acs.org/doi/abs/10.1021/jo00365a008 ''J. Org. Chem.'' '''1986''', ''51'', 2899 – 2901]. | |||
35. ''Carbene Rearrangements XX:'' "''trans''–2–(1,3–Butadienyl)cyclopropylidene: Generation and Reactive Behavior," Brinker, U. H.; Fleischhauer, I. [https://doi.org/10.1002/cber.19861190414 ''Chem. Ber.'' '''1986''', ''119'', 1244 – 1268 (in German)]. | |||
34. "Bicyclo[4.1.1]octa–2,4–dien–7–one," König, L.; Brinker, U. H. [https://doi.org/10.1002/cber.19861190134 ''Chem. Ber.'' '''1986''', ''119'', 383 – 386 (in German)]. | |||
33. ''Carbene Rearrangements XIX:'' "1,1– ''versus'' 1,6–Dehalogenation in ''gem''–Dibromocyclopropanes. Synthesis of Benzo–''anti''–σ–bishomobenzene," Brinker, U. H.; Wüster, H.; Maas, G. [http://pubs.rsc.org/en/content/articlepdf/1985/c3/C39850001812 ''J. Chem. Soc., Chem. Commun.'' '''1985''', 1812 – 1814]. | |||
32. ''Carbene Rearrangements XVIII'': "Spiroacetal Formation by Carbene (Carbenoid) Insertion Reaction: Synthesis of the Major Constituent of the Sex Attractant of the Olive Fly (''Dacus oleae'')," Brinker, U. H.; Haghani, A.; Gomann, K. [https://doi.org/10.1002/anie.198502301 ''Angew. Chem.'' '''1985''', ''97'', 235 – 236]; [https://doi.org/10.1002/anie.198502301 ''Angew. Chem., Int. Ed. Engl.'' '''1985''', ''24'', 230 – 231]. | |||
==1980 – 1984== | |||
31. ''Carbene Rearrangements XVII:'' "Spiro[2.3]hexanes by C4 + C2 – Coupling," Brinker, U. H.; Boxberger, M. [https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.198409741 ''Angew. Chem.'' '''1984,''' ''96'', 971 – 972]; [https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.198409741 ''Angew. Chem., Int. Ed. Engl.'' '''1984,''' ''23'', 974 – 975]. | |||
30. ''Carbene Rearrangements XVI:'' "Bicyclo[3.2.1]octa–2,6–dien–8–ylidene (Homo–7–norbornadienylidene), a 'Foiled' Carbene," Brinker, U. H.; König, L. [https://doi.org/10.1246/cl.1984.45 ''Chem. Lett.'' '''1984''', 45 – 48]. | |||
29. "Washington, D(ivalent) C(arbon)," Brinker, U. H. [https://doi.org/10.1002/nadc.19830311210 ''Nachr. Chem. Techn. Lab. '''''1983''', 974 – 978 (in German)]. | |||
28. "Tricyclo[4.1.0.0<sup>1,3</sup>]hept–4–enes as Intermediates," Brinker, U. H.; Gomann, K.; Zorn, R. [https://doi.org/10.1002/anie.198312410 ''Angew. Chem. Suppl.'' '''1983''', 1241 – 1255 (in German)]. | |||
27. ''Carbene Rearrangements XV:'' "Tricyclo[4.1.0.0<sup>1,3</sup>]hept–4–enes as Intermediates," Brinker, U. H.; Gomann, K; Zorn, R. [https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.198308691 ''Angew. Chem.'' '''1983''', ''95'', 893 – 894]; | |||
[https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.198308691 ''Angew. Chem., Int. Ed. Engl.'' '''1983''', ''22'', 869 – 870]. | |||
26. "Thermolysis and Reactions of 4,5–Benzotricyclo[4.1.0.0<sup>1,3</sup>]hept–4–ene and ''o''–(Propadienyl)styrene," Brinker, U. H.; Wilk, G.; Gomann, K. [https://doi.org/10.1002/anie.198312280 ''Angew. Chem. Suppl.'' '''1983''', 1228 – 1239 (in German)]. | |||
25. "Thermolysis and Reactions of 4,5–Benzotricyclo[4.1.0.0<sup>1,3</sup>]hept–4–ene and ''o''–(Propadienyl)styrene," Brinker, U. H.; Wilk, G.; Gomann, K. [http://onlinelibrary.wiley.com/doi/abs/10.1002/anie.198308681 ''Angew. Chem.'' '''1983''', ''95'', 892 – 893]; [https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.198308681 ''Angew. Chem., Int. Ed. Engl.'' '''1983''', ''22,'' 868 – 869]. | |||
24. ''Carbene Rearrangements XIV:'' "Regiospecific Rearrangements of Vinyl– and Butadienyl–substituted Cyclopropylidenes," Fleischhauer, I.; Brinker, U. H. [https://doi.org/10.1016/S0040-4039(00)88136-8 ''Tetrahedron Lett.'' '''1983''', ''24'', 3205 – 3208 (in German)]. | |||
23. ''Carbene Rearrangements XIII:'' "Substituted Pyrroles by Carbene–Carbene Rearrangements," Brinker, U. H.; Boxberger, M. [https://www.newkai.com/uhb3/images/4/46/B24-0135.pdf ''J. Chem. Res. (S)'' '''1983''', 100 – 101]. | |||
22. ''Carbene Rearrangements XI:'' "Bicyclo[4.1.1]oct–2–en–7–yliden," Brinker, U. H.; König, L. [https://doi.org/10.1002/cber.19831160308 ''Chem. Ber.'' '''1983''', ''116'', 894 – 910]. | |||
21. ''Carbene Rearrangements X:'' "2–Vinylcyclobutyliden," Brinker, U. H.; König, L. [https://doi.org/10.1002/cber.19831160307 ''Chem. Ber.'' '''1983''', ''116'', 882 – 893]. | |||
20. ''Carbene Rearrangements XII:'' "''tert''-Butylcarbene from 1,1–Diiodoneopentane," Fukushima, M.; Jones, Jr., M.;* Brinker, U. H. [https://doi.org/10.1016/S0040-4039(00)87572-3 ''Tetrahedron Lett''. '''1982''', ''23'', 3211 – 3214]. | |||
19. ''Carbene Rearrangements IX:'' "Cyclobutylidenes from Geminal Dihalogenocyclobutanes," Brinker, U. H.; Schenker, G. [https://doi.org/10.1039/C39820000679 ''J. Chem. Soc., Chem. Commun.'' '''1982''', 679 – 681]. | |||
18. ''Carbene Rearrangements VIII'': "Carbene–Carbene Rearrangements as a Route to 1,5–Dihydropentalene," Brinker, U. H.; Fleischhauer, I. In ''Developments in Polycyclopentanoid Chemistry;'' Paquette, L. A., Ed.; Tetrahedron Symposia-in-Print, [https://doi.org/10.1016/0040-4020(81)80016-6 ''Tetrahedron '''''1981''', ''37'', 4495 – 4502]. | |||
17. ''Carbene Rearrangements VII:'' "Temperature Dependence of Carbene–Carbene Rearrangements. A New Method for the Generation of Carbenes," Brinker, U. H.; Ritzer, J. [http://pubs.acs.org/doi/pdf/10.1021/ja00398a052 ''J. Am. Chem. Soc.'' '''1981''', ''103'', 2116 – 2119]. | |||
16. ''Carbene Rearrangements VI'': "Evidence for a Novel Carbene–Carbene Rearrangement of a New Foiled Methylene," Brinker, U. H.; König, L. [http://pubs.acs.org/doi/abs/10.1021/ja00391a050 ''J. Am Chem. Soc.'' '''1981''', ''103'', 212 – 214]. | |||
15. ''Carbene Rearrangements V:'' "4,5–Benzotricyclo[4.1.0.0<sup>1,3</sup>]hept–4–ene," Brinker, U. H.; Streu, J. [http://onlinelibrary.wiley.com/doi/abs/10.1002/anie.198006311 ''Angew. Chem.'' '''1980''', ''92'', 641 – 642]; [http://onlinelibrary.wiley.com/doi/abs/10.1002/anie.198006311 ''Angew. Chem., Int. Ed. Engl.'' '''1980,''' ''19'', 631 – 632]. | |||
14. "Towards a Classification of Singlet Carbenes," Schoeller, W. W.; Brinker, U. H. [https://www.newkai.com/uhb3/images/a/ac/Schoeller%26UHB-ZNat.1980.pdf ''Z. Naturforsch. - A Journal of Chemical Sciences '''''1980''', ''35 b'', 475 – 476]. | |||
13. ''Carbene Rearrangements IV:'' "1,5–Dihydropentalene by Tandem Carbene–Carbene Rearrangement," Brinker, U. H.; Fleischhauer, I. [http://onlinelibrary.wiley.com/doi/abs/10.1002/anie.198003041 ''Angew. Chem.'' '''1980,''' ''92'', 314 – 315]; [http://onlinelibrary.wiley.com/doi/abs/10.1002/anie.198003041 ''Angew. Chem., Int. Ed. Engl.'' '''1980,''' ''19'', 304 – 305]. | |||
==1970 – 1979== | |||
12. ''Carbene Rearrangements III:'' "Carbene Rearrangements of 2–Vinylcyclobutylidene," Brinker, U. H.; König, L. [http://pubs.acs.org/doi/pdf/10.1021/ja00510a055 ''J. Am. Chem. Soc.'' '''1979''', ''101'', 4738 – 4739]. | |||
11. ''Carbene Rearrangements II:'' "Carbene–Carbene Rearrangements of ''cis''– and ''trans''–2–(1,3–Butadienyl)cyclopropylidene," Brinker, U. H.; Fleischhauer, I. [http://onlinelibrary.wiley.com/doi/abs/10.1002/anie.197903961 ''Angew. Chem.'' '''1979''', ''91'', 424 – 425] [http://onlinelibrary.wiley.com/doi/abs/10.1002/anie.197903961''Angew. Chem., Int. Ed. Engl.'' '''1979''', ''18'', 396 – 397]. | |||
10. ''Carbene Rearrangements I:'' "On the Thermal Reaction of Vinylcyclopropylidene to Cyclopentenylidene. An Exploration of the Electronic Hypersurface," Schoeller, W. W.; Brinker, U. H. [http://pubs.acs.org/doi/pdf/10.1021/ja00487a006 ''J. Am. Chem. Soc.'' '''1978''', ''100'', 6012 – 6017]. | |||
9. "Generation and Properties of 4,9– and 3,8–Methano[11]annulenylidenes," Jones, W. M.; LaBar, R. A.; Brinker, U. H.; Gebert, P. H. [https://www.newkai.com/uhb3/images/9/94/Jones-et-al-2002-generation-and-properties-of-4-9-and-3-8-methano-11-annulenylidenes.pdf ''J. Am. Chem. Soc.'' '''1977''', ''99'', 6379 – 6391]. | |||
8. "Bridged 22π Annulenes from 6,11–Methano[11]annulenylidene," Brinker U. H.; King, R. W.; Jones, W. M. [https://doi.org/10.1021/ja00451a059 ''J. Am. Chem. Soc.'' '''1977''', ''99'', 3175 – 3177]. | |||
7. "Some Pericyclic Reactions of Carbenes," Jones, W. M.; Brinker, U. H. In: ''Pericyclic Reactions,'' A Series of Monographs: Organic Chemistry [http://dx.doi.org/10.1016/B978-0-12-470501-2.50009-7 Vol. 35, Part 1, Marchand, A. P.; Lehr, R. E., Eds., Academic Press: New York, 1977, Chapter 3, pp. 109 – 198]. | |||
6. "A Facile Photochemically Induced Arylcarbene – Aromatic Carbene Rearrangement in Solution," Brinker, U. H.; Jones, W. M. [https://doi.org/10.1016/S0040-4039(00)77915-9 ''Tetrahedron Lett.'' '''1976''', ''17'', 577 – 580]. | |||
5. "2,3–Dichloro–5,6–dicyano–''p''–benzoquinone (DDQ); A New Inexpensive Recovery by Anodic Oxidation of 2,3–Dichloro–5,6–dicyano–''p''–hydroquinone (DDH)," Brinker, U. H.; Tyner III, M.; Jones, W. M. [https://www.researchgate.net/publication/235706637_23-Dichloro-56-dicyano-p-benzoquinone_DDQ_A_New_Inexpensive_Recovery_by_Anodic_Oxidation_of_23-Dichloro-56-dicyano-p-hydroquinone_DDH ''Synthesis'' '''1975''', 671]. | |||
4. "Potential Homoaromatic Compounds with 10 and 14π Electron Systems," Brinker, U. H., Doctoral Dissertation (Dr. rer. nat.), University of Cologne, Federal Republic of Germany, 1973, self-published (in German). | |||
3. "Significance of Stereochemical Factors for the Chemical Shift of the <sup>13</sup>C Resonance," Günther, H.;* Schmickler, H.; Brinker, U. H.; Nachtkamp, K.; Wassen, J.; Vogel, E. [http://onlinelibrary.wiley.com/doi/abs/10.1002/anie.197307601 ''Angew. Chem.'' '''1973''', ''85'', 762 – 763] ; [http://onlinelibrary.wiley.com/doi/abs/10.1002/anie.197307601 ''Angew. Chem., Int. Ed. Engl.'' '''1973''', ''12'', 760 – 761]. | |||
2. "Semibullvalenes as Potential Homoaromatic Compounds," Vogel, E.; Brinker, U. H.; Nachtkamp, K.; Wassen, J.; Müllen, K. [http://onlinelibrary.wiley.com/doi/abs/10.1002/anie.197307581 ''Angew. Chem.'' '''1973''', ''85'', 760 – 762]; [http://onlinelibrary.wiley.com/doi/abs/10.1002/anie.197307581''Angew. Chem., Int. Ed. Engl.'' '''1973''', ''12'', 758 – 760]. | |||
1. "Growing of Chalcogenide Single Crystals by Chemical Transport with Aluminum Chloride," Lutz, H. D.;* Lovász, C.; Bertram, K. H.; Srećković, M.; Brinker, U. | |||
[https://www.newkai.com/uhb3/images/4/48/BF00910239.pdf ''Monatsh. Chem.'' '''1970''', ''101'', 519 – 524 (in German)]. | |||
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